Fics like Lightning in a Bottle

Zuko falls asleep, 23 years old and the reigning Firelord of 8 years. Zuko wakes up, 3 years old and fourth in line for the Dragon Throne. After realizing his position, Zuko begins working to cultivate a better future for himself and his sister, Azula, who he desperately wishes to save from a terrible fate. With the power and knowledge of an adult, Zuko manages to save himself and his sister from being hurt, but how long will that last? Now he must help the Avatar, by teaching him firebending and protecting him until he is fully realized. Can he do it? Or will Zuko crumble under the pressure of the entire future resting on his shoulders?

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