Fics like Whiskey and Scents

Dean was an alpha, and Castiel was, conveniently, one of the few omegas in existence. He knew from years of exploiting his designation that just a whiff of him was enough to make any alpha discard all common sense, and he didn’t expect Dean to be any different from his past targets. He would deal with him like he had all the others: seduce him, lead him to bed, then shoot him in the head- nothing simpler. Castiel is given the task of dispatching kingpin of the local black market, Dean Winchester. The man isn't at all who Castiel expects him to be.

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